WebApr 22, 2014 · Surface grafting of vinyl-functionalized poly (fluorene)s via thiol-ene click chemistry. Langmuir. 2014 Apr 22;30 (15):4427-33. doi: 10.1021/la5000588. WebFor thiol-ene reactions that are chain transfer limited, the radical that is formed from the addition step is somewhat stable, and therefore slower to abstract a thiol hydrogen [21]. ... A.B. Lowe, C.N. Bowman, Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis, Chem. Soc. Rev. 39 (4) (2010) 1355e1387, https ...
Radical-mediated thiol–ene ‘click’ reactions in ... - ScienceDirect
WebFor thiol-ene reactions that are chain transfer limited, the radical that is formed from the addition step is somewhat stable, and therefore slower to abstract a thiol hydrogen [21]. … WebAug 19, 2013 · The key attribute of the thiol-Michael addition reaction that makes it a prized tool in materials science is its modular “click” nature, which allows for the implementation … bomis logo
Exploring the advantages of oxygen-tolerant thiol-ene ... - Nature
WebInitial studies into the compatibility of selected DESs as shown in Table 1 with the thiol–ene reaction commenced with a screen of a range of common DES solvents. Reaction mixtures underwent irradiation at 365 nm for 1 hour, after which time the reaction was diluted with H 2 O and extracted with EtOAc. Reaction products together with decomposed initiator 2,2 … In organosulfur chemistry, the thiol-ene reaction (also alkene hydrothiolation) is an organic reaction between a thiol (R−SH) and an alkene (R2C=CR2) to form a thioether (R−S−R’). This reaction was first reported in 1905, but it gained prominence in the late 1990s and early 2000s for its feasibility and wide range of … See more Radical addition Thiol-ene additions are known to proceed through two mechanisms: free-radical additions and catalyzed Michael additions. Free-radical additions can be initiated by light, heat or radical … See more Initiation of cascade cyclization The thiol-ene reaction (and analogous thiol-yne reaction) have extensively been used in generating reactive … See more • Click chemistry • Thiol-yne reaction • Off-stoichiometry thiol-ene polymer • Free-radical addition See more Click chemistry reactions are known to be high efficiency and have fast reaction rates, yet there is considerable variability in the overall reaction rate depending on the functionality of the alkene. To better understand the kinetics of thiol-ene reactions, … See more Dendrimer synthesis Dendrimers are promising in medicine, biomaterials, and nanoengineering. These polymers can … See more WebThe thiol-yne reaction (also known as alkyne hydrothiolation) is an organic reaction between a thiol and an alkyne. The reaction product is an alkenyl sulfide. [1] [2] The reaction was first reported in 1949 with thioacetic acid as reagent [3] [4] and rediscovered in 2009. [5] It is used in click chemistry [6] [7] [8] and in polymerization ... bo mirhosseni